Crystal engineering provides life to Perovskite photo voltaic cells


Michael Grätzel EPFL

One in every of them was the invention that selling (111) crystal aspects on the floor of perovskite skinny movies makes them extra steady within the face of warmth, gentle and moisture, in response to EPFL, which labored on this case with Sungkyunkwan College South Korea.

The researchers checked out aspects on the floor of perovskite skinny movies: (100) aspects, mostly discovered, and the rarer (111) aspects.

“The examine discovered that the (100) aspect is especially susceptible to degradation as it might rapidly transition to an unstable, inactive part when uncovered to moisture,” in response to EPFL. “In distinction, the (111) aspect was discovered to way more steady and proof against degradation.”


The reason for degradation was water bonding with the (100) aspects on the movie’s floor, resulting in instability.

Including ligand molecules to advertise development of the extra steady (111) aspect on the movie’s floor, which EPFL is looking aspect engineering, made movies that have been “exceptionally steady and proof against each moisture and warmth”, it mentioned.

Stability was reported towards moisture as much as 85% relative humidity and temperatures as much as 85°C with out extra floor passivation.

The work is roofed within the paper ‘Unveiling facet-dependent degradation and aspect engineering for steady perovskite photo voltaic cells‘, revealed by Science.

Only some days earlier in the identical journal, this time with different collaborators, EPFL revealed one other paper on longer-life thin-film perovskite photo voltaic cells, created by a pair of modifications.

An additive was used to consolidate the crystal construction by engineering the grain boundaries – which elevated tolerance to illumination, warmth and moisture, and a modification was made to injected holes into the hole-transport materials, successfully p-doping it.

The ensuing cells achieved 23.5% effectivity in a 1cm2 blended–cation-anion perovskite photo voltaic cell, and 21.4% for 17.1cm2 perovskite photo voltaic module – the latter retaining 95.5% of its preliminary effectivity after >3,000h underneath one-sun illumination at 70°C.

For this one, EPFL labored with: Huazhong College of Science and Know-how, Wuhan College of Know-how, Southern College of Science and Know-how (Shenzhen), Wuhan College and the Chinese language Academy of Sciences. It’s revealed as ‘Radical polymeric p-doping and grain modulation for steady, environment friendly perovskite photo voltaic modules‘.





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